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Spatially resolved measurement of electrochemical activity and pH distributions in corrosion processes by scanning electrochemical microscopy using antimony microelectrode tips
dc.contributor.author | Souto, Ricardo Manuel | |
dc.contributor.author | Izquierdo Pérez, Javier | |
dc.contributor.author | Nagy, Lívia | |
dc.contributor.author | Varga, Ágnes | |
dc.contributor.author | Santana, Juan José | |
dc.contributor.author | Nagy, Géza | |
dc.date.accessioned | 2020-03-30T11:46:34Z | |
dc.date.available | 2020-03-30T11:46:34Z | |
dc.date.issued | 2011 | es_ES |
dc.identifier.uri | http://riull.ull.es/xmlui/handle/915/19139 | |
dc.description.abstract | A new method for the spatially-resolved measurement of pH during corrosion processes with the scanning electrochemical microscope (SECM) is presented. Antimony tips are employed because the dual-function characteristics of this material allow the combined amperometric/potentiometric operation of the SECM. The applicability of this technique is illustrated by considering the galvanic corrosion of a model zinc-iron pair immersed in 0.1 M NaCl aqueous solution. Spatially resolved images of pH and oxygen concentration above the metal specimens could be obtained in the same experiment. | en |
dc.format.mimetype | application/pdf | |
dc.language.iso | en | es_ES |
dc.relation.ispartofseries | Electrochimica Acta, 56, 8846-8850 (2011) | es_ES |
dc.rights | Licencia Creative Commons (Reconocimiento-No comercial-Sin obras derivadas 4.0 Internacional) | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/deed.es_ES | |
dc.title | Spatially resolved measurement of electrochemical activity and pH distributions in corrosion processes by scanning electrochemical microscopy using antimony microelectrode tips | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1016/j.electacta.2011.07.076 | |
dc.subject.keyword | Scanning electrochemical microscopy | en |
dc.subject.keyword | galvanic corrosion | en |
dc.subject.keyword | pH distribution | en |
dc.subject.keyword | antimony microelectrode | en |