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Scanning microelectrochemical characterization of the anti-corrosion performance of inhibitor films formed by 2-mercaptobenzimidazole on copper
dc.contributor.author | Souto, Ricardo Manuel | |
dc.contributor.author | Izquierdo Pérez, Javier | |
dc.contributor.author | Santana, Juan José | |
dc.contributor.author | González, Sergio | |
dc.date.accessioned | 2020-03-30T19:55:37Z | |
dc.date.available | 2020-03-30T19:55:37Z | |
dc.date.issued | 2012 | |
dc.identifier.uri | http://riull.ull.es/xmlui/handle/915/19161 | |
dc.description.abstract | The aim of this work is to explore the applicability of the scanning electrochemical microscope (SECM) to characterize the inhibiting effect of 2-mercaptobenzimidazole against the corrosion of copper. SECM was operated in the feedback mode by using ferrocene-methanol as redox mediator, and the sample was left unbiased at all times. The kinetic changes in the corrosion processes were monitored over time from the Z-approach curves. Furthermore, inhibitor-modified copper samples presenting various surface finishes were imaged by SECM and the scanning vibrating electrode technique (SVET), allowing changes both in the surface activity of metal-inhibitor films and in the extent of corrosion attack to be spatially-resolved. Differences in the local electrochemical activity between inhibitor-free and inhibitor-covered areas of the sample were successfully monitored | en |
dc.format.mimetype | application/pdf | |
dc.language.iso | en | |
dc.relation.ispartofseries | Progress in Organic Coatings, 74, 526-533 (2012) | |
dc.rights | Licencia Creative Commons (Reconocimiento-No comercial-Sin obras derivadas 4.0 Internacional) | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/deed.es_ES | |
dc.title | Scanning microelectrochemical characterization of the anti-corrosion performance of inhibitor films formed by 2-mercaptobenzimidazole on copper | en |
dc.type | info:eu-repo/semantics/article | |
dc.identifier.doi | 10.1016/j.porgcoat.2012.01.019 | |
dc.subject.keyword | Corrosion inhibition | en |
dc.subject.keyword | Scanning electrochemical microscopy | en |
dc.subject.keyword | Scanning Vibrating Electrode Technique | en |
dc.subject.keyword | Copper | en |
dc.subject.keyword | Mercaptobenzimidazole | en |