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dc.contributor.authorDare, Enock O.
dc.contributor.authorVendrell-Criado, Victoria
dc.contributor.authorJiménez, M. Consuelo
dc.contributor.authorPérez-Ruiz, Raúl
dc.contributor.authorDíaz Díaz, David
dc.date.accessioned2020-09-28T11:08:54Z
dc.date.available2020-09-28T11:08:54Z
dc.date.issued2020
dc.identifier.urihttp://riull.ull.es/xmlui/handle/915/21324
dc.description.abstractThe recent demand for fluorescent labeled materials (FLMs) in forensic security concepts such as latent fingerprints (LFs) that encodes information for anti-counterfeiting and encryption of confidential data makes necessary the development of building new and innovative materials. Here, novel FLMs based on Polyhedral Oligomeric Silsesquioxanes (POSS) functionalized with fluorophores via “click” reactions have been successfully synthesized and fully characterized. A comprehensive study of their photophysical properties has displayed large Stokes’s shift together with good photostability in all cases, fulfilling the fundamental requisites for any legible LF detection on various surfaces. The excellent performance of the hetero-bifunctional FLM in the visualization of LF is emphasized by their legibility, selectivity, sensitivity and temporal photostability. In this study, development mechanisms have been proposed and the overall concept constitute a novel approach for vis-à-vis forensic investigations to trace an individual’s identity.es_ES
dc.description.sponsorshipAlexander von Humboldt Foundationes_ES
dc.description.sponsorshipGeneralitat Valencianaes_ES
dc.description.sponsorshipUniversität Regensburges_ES
dc.description.sponsorshipUniversidad de La Lagunaes_ES
dc.description.sponsorshipMinisterio de Ciencia, Innovación y Universidadeses_ES
dc.language.isoenes_ES
dc.publisherWileyes_ES
dc.relation.ispartofseriesChemistry - A European Journal, 2020;
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.titleNovel Fluorescent Labeled Octasilsesquioxanes Nanohybrids as Potential Materials for Latent Fingerprinting Detectiones_ES
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doi10.1002/chem.202001908
dc.relation.projectIDCIDEGENT/2018/044es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.subject.keywordsilsesquioxaneses_ES
dc.subject.keywordfluorophoreses_ES
dc.subject.keywordclick chemistryes_ES
dc.subject.keywordfingerprint identificationes_ES
dc.subject.keywordphotostabilityes_ES
dc.subject.keywordidentificación de huellas dactilareses_ES
dc.subject.keywordfotoestabilidades_ES
dc.subject.keywordsilsesquioxanoes_ES
dc.subject.keywordfluoróforoes_ES
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersiones_ES


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Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivatives 4.0 Internacional