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dc.contributor.authorSouto, Ricardo Manuel 
dc.contributor.authorFilotás, Dániel
dc.contributor.authorFernández-Pérez, Bibliana María
dc.contributor.authorNagy, Lívia
dc.contributor.authorNagy, Géza
dc.contributor.otherQuímica
dc.contributor.otherProyecto CTQ2018-80522-P Grupo de Electroquímica y Corrosión, Instituto de Materiales y Nanotecnología
dc.date2021
dc.date.accessioned2021-08-25T10:45:24Z
dc.date.available2021-08-25T10:45:24Z
dc.identifier.urihttp://riull.ull.es/xmlui/handle/915/25211
dc.description.abstractWith the goal to facilitate a new experimental procedure for the monitoring of anomalous hydrogen evolution from anodically-polarized magnesium-based materials, this paper presents the application of the three-step (off-on-off) anodization operation sequence for amperometric scanning electrochemical microscopy (SECM) recently by our group to the characterization of 99.9% magnesium in aqueous saline solution. The SECM measurements done above prepolarized and nonpolarized magnesium provided new information on the hydrogen evolution reaction (HER) on this metal, whereas other experiments are presented that enable to monitor the effect of the oxy-hydroxide layer formed on the metal under anodic polarization. In addition, direct comparison of the data obtained for 99.9% magnesium with those previously obtained for AZ63 magnesium alloy contributed to separate the effect of noble impurities from the catalytic effect of the oxy-hydroxide layer formed on magnesium for the hydrogen-evolution reactionen
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.relation.ispartofseriesJournal of Electroanalytical Chemistry, 895 (2021)en
dc.rightsLicencia Creative Commons (Reconocimiento-No comercial-Sin obras derivadas 4.0 Internacional)
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/deed.es_ES
dc.titleInvestigation of anomalous hydrogen evolution from anodized magnesium using a polarization routine for scanning electrochemical microscopyen
dc.typeinfo:eu-repo/semantics/article
dc.identifier.doihttps://doi.org.10.1016/j.jelechem.2021.115538
dc.subject.keywordanodic polarizationen
dc.subject.keywordanomalous hydrogen evolutionen
dc.subject.keywordcorrosionen
dc.subject.keywordmagnesiumen
dc.subject.keywordscanning electrochemical microscopyen


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