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In-situ measurement of electrochemical activity related to filiform corrosion in organic coated steel by scanning vibrating electrode technique and scanning micropotentiometry
| dc.contributor.author | Souto, Ricardo Manuel | |
| dc.contributor.author | Cristoforetti, A. | |
| dc.contributor.author | Izquierdo, Javier | |
| dc.contributor.author | Deflorian, F. | |
| dc.contributor.author | Fedel, M. | |
| dc.contributor.author | Rossi, S. | |
| dc.contributor.other | Química | |
| dc.contributor.other | Grupo de Electroquímica y Corrosión (IMN-ULL) | |
| dc.date.accessioned | 2023-11-28T21:05:12Z | |
| dc.date.available | 2023-11-28T21:05:12Z | |
| dc.date.issued | 2024 | |
| dc.identifier.uri | http://riull.ull.es/xmlui/handle/915/34616 | |
| dc.description.abstract | A new approach to studying the mechanism of filiform corrosion in organic coated steel based on the scanning vibrating electrode technique (SVET) and micropotentiometry (potentiometric SECM) is presented. The elec trochemical activity of the process under the coating is evaluated by mapping the ionic current densities emanating from some artificial defects made in specific locations of the filament identifiable thanks to the transparency of the coating. In addition, antimony tips are employed to investigate the pH changes associated to the different corrosion reactions at the metal-paint interface. Local pH levels associated to anodic and cathodic regions are determined along the filament. | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | en | |
| dc.relation.ispartofseries | Corrosion Science, 227 (2024) | |
| dc.rights | Licencia Creative Commons (Reconocimiento-No comercial-Sin obras derivadas 4.0 Internacional) | |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/deed.es_ES | |
| dc.title | In-situ measurement of electrochemical activity related to filiform corrosion in organic coated steel by scanning vibrating electrode technique and scanning micropotentiometry | en |
| dc.type | info:eu-repo/semantics/article | |
| dc.identifier.doi | 10.1016/j.corsci.2023.111669 | |
| dc.subject.keyword | Organic coatings | en |
| dc.subject.keyword | Steel | en |
| dc.subject.keyword | Scanning vibrating electrode technique | en |
| dc.subject.keyword | Scanning electrochemical microscopy | en |
| dc.subject.keyword | Potentiometry | en |
| dc.subject.keyword | Anodic dissolution | en |
| dc.subject.keyword | Atmospheric corrosion | en |
| dc.subject.keyword | Paint coatings | en |
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