RT info:eu-repo/semantics/article T1 Evaluation of the corrosion protection of steel by anodic processing in metasilicate solution using the scanning vibrating electrode technique A1 Izquierdo Pérez, Javier A1 Fernández-Pérez, Bibliana María A1 Martín-Ruíz, L. A1 Mena, Víctor A1 Rodríguez Raposo, Raquel A1 Santana, Juan José K1 corrosion protection K1 steel K1 metasilicate ions K1 surface modification K1 anodic treatment K1 scanning vibrating electrode technique AB Anodic processing in metasilicate solution was investigated for the improvement of the corrosion resistance of various steels, namely F111 low alloy carbon and 304 stainless steels, as well as on galvanized steel cut edges. The efficiency of the prior electrochemical treatment for each material was tested during their exposure to naturally-aerated aqueous chloride solutions of different aggressiveness. Analysis was performed using the scanning vibrating electrode technique (SVET) in order to detect local ionic current distributions over the samples under study associated to the corrosion reactions. The onset of corrosion processes were greatly inhibited after anodic processing with metasilicate on both the low alloy carbon steel and the galvanized steel cut edge. Conversely, SVET analysis of unbiased 304 steel samples tested in 0.1 M chloride-containing solution did not show differences between pristine and metasilicate-treated surfaces. Differences in the electrochemical reactivity between treated and non-treated 304 steel surfaces were only observed after partial removal of the corresponding passive layers under operator-controlled polarization. YR 2015 FD 2015 LK http://riull.ull.es/xmlui/handle/915/19061 UL http://riull.ull.es/xmlui/handle/915/19061 LA en DS Repositorio institucional de la Universidad de La Laguna RD 24-nov-2024