RT info:eu-repo/semantics/article
T1 Core-shell poly(dopamine) magnetic nanoparticles for the extraction of estrogenic mycotoxins from milk and yogurt prior to LC-MS analysis
A1 González Sálamo, Javier
A1 Hernández Borges, Javier
A1 Socas Rodríguez, Bárbara
A1 Rodríguez Delgado, Miguel Ángel
A2 Química
K1 Mycotoxin Milk Poly(dopamine)
K1 Magnetic nanoparticles
K1 Dispersive solid-phase extraction
K1 LC–MS
AB In this work, core-shell poly(dopamine) magnetic nanoparticles synthesized in our laboratory have been applied as dispersive solid-phase extraction (dSPE) sorbent for the extraction of a group of six mycotoxins of interest including zearalenone, a-zearalanol, b-zearalanol, a-zearalenol, b-zearalenol and zearalanone, from complex matrices such as milk (whole and skimmed cow milk and semi-skimmed goat milk) and yogurt (an unsweetened natural yogurt) prior to their LC–MS analysis. 17b-estradiol-D5 was used as internal standard. The procedure includes a deproteinization step prior to the extraction procedure. Matrix-matched calibration and a recovery study were carried out in the selected matrices, providing good linearity, relative recovery values in the range 70–120% with RSDs lower than 16% and LODs between 0.21 and 4.77 lg/L for milk samples and between 0.29 and 4.54 lg/kg for yogurt samples.
YR 2017
FD 2017
LK http://riull.ull.es/xmlui/handle/915/36090
UL http://riull.ull.es/xmlui/handle/915/36090
LA en
NO Food Chemistry 215 (2017) 362-368https://doi.org/10.1016/j.foodchem.2016.07.154
DS Repositorio institucional de la Universidad de La Laguna
RD 27-dic-2024