RT info:eu-repo/semantics/article
T1 Expanding the use of polymeric ionic liquids in headspace solid-phase microextraction: Determination of ultraviolet filters in water samples
A1 Trujillo Rodríguez, María José
A1 Nan, He
A1 Anderson, Jared L.
K1 Polymeric ionic liquids
K1 Headspace solid-phase microextraction
K1 Gas chromatography–mass spectrometry
K1 Ultraviolet filters
K1 Water analysis
AB Three crosslinked polymeric ionic liquid (PIL) sorbent coatings were used in headspace solid-phase microextraction for the determination of a group of ultraviolet filters. The developed crosslinked PILbased materials include two polycations and a double confined PIL. The method, in combination with gas chromatography-mass spectrometry, is simple, solvent free, and does not require of any derivatization step. After proper optimization of the methodologies with each developed fiber, the analytical performance was compared with a commercial polyacrylate fiber. A study of the normalized calibration slopes, obtained by dividing the calibration slope of each analyte by the coating volume, revealed that the crosslinked fibers can be used as alternatives to commercial fibers for the determination of the selected group of compounds. In particular, the coating nature of the PIL containing the 1-vinylbenzyl-3-hexadecylimidazolium bis[(trifluoromethyl)sulfonyl]imide IL as monomer and the 1,12di(3-vinylbenzylimidazolium)dodecane bis[(trifluoromethyl)sulfonyl]imide IL as crosslinker is the most suitable for the extraction of the selected compounds despite their coating volume, being 3.6 times lower than the commercial polyacrylate fiber. For this fiber, wide linear ranges, correlation coefficients higher than 0.990, limits of detection ranging from 2.8 ng L−1to 26 ng L−1and relative standard deviations ranging from 2.5 to 15% were achieved. Finally, all proposed PIL-based fibers were applied towards the analysis of tap water, pool water and lake water, with the majority of the ultraviolet filters being detected and quantified in the last two types of samples.
YR 2018
FD 2018
LK http://riull.ull.es/xmlui/handle/915/36155
UL http://riull.ull.es/xmlui/handle/915/36155
LA en
NO Journal of Chromatography A10.1016/j.chroma.2018.01.048
DS Repositorio institucional de la Universidad de La Laguna
RD 27-dic-2024