RT info:eu-repo/semantics/article T1 Modification of the corrosion response of steel substrates by ion-nitriding A1 Souto, Ricardo Manuel A1 Alanyali, Hasan A1 Rodríguez Raposo, Raquel A1 Fernández-Mérida, Luis A1 González, Sergio A2 Química A2 Grupo de Electroquímica y Corrosión Departamento de Química Instituto de Materiales y Nanotecnología K1 Corrosion K1 ion nitriding K1 thin inorganic coatings K1 steels K1 electrochemical impedance spectroscopy AB This paper concentrates on the electrochemical behaviour of ion-nitrided coatings produced by cathodic arc plasma deposition. The corrosion of five different steel grades modified by ion-nitriding was investigated through electrochemical polarization and electrochemical impedance spectroscopy techniques in immersion tests performed in a 0.5 M NaCl solution. Ion-nitrided and bare steel substrates were employed. Enhanced corrosion resistance is found for the coated steels. A porous film is produced on the metallic substrates, which allows for electrochemical reactive areas to be developed inside the pores. Surface film breakdown results in the localised corrosion of the materials at potentials positive to the corresponding pitting potential values for each material in the testing solution YR 2013 FD 2013 LK http://riull.ull.es/xmlui/handle/915/19022 UL http://riull.ull.es/xmlui/handle/915/19022 LA en DS Repositorio institucional de la Universidad de La Laguna RD 23-may-2024