RT info:eu-repo/semantics/article T1 In-situ measurement of electrochemical activity related to filiform corrosion in organic coated steel by scanning vibrating electrode technique and scanning micropotentiometry A1 Souto, Ricardo Manuel A1 Cristoforetti, A. A1 Izquierdo, Javier A1 Deflorian, F. A1 Fedel, M. A1 Rossi, S. A2 Química A2 Grupo de Electroquímica y Corrosión (IMN-ULL) K1 Organic coatings K1 Steel K1 Scanning vibrating electrode technique K1 Scanning electrochemical microscopy K1 Potentiometry K1 Anodic dissolution K1 Atmospheric corrosion K1 Paint coatings AB A new approach to studying the mechanism of filiform corrosion in organic coated steel based on the scanning vibrating electrode technique (SVET) and micropotentiometry (potentiometric SECM) is presented. The elec trochemical activity of the process under the coating is evaluated by mapping the ionic current densities emanating from some artificial defects made in specific locations of the filament identifiable thanks to the transparency of the coating. In addition, antimony tips are employed to investigate the pH changes associated to the different corrosion reactions at the metal-paint interface. Local pH levels associated to anodic and cathodic regions are determined along the filament. YR 2024 FD 2024 LK http://riull.ull.es/xmlui/handle/915/34616 UL http://riull.ull.es/xmlui/handle/915/34616 LA en DS Repositorio institucional de la Universidad de La Laguna RD 17-may-2024